Prof. Jeremiah A Johnson

A Thomas (1960) and Diane W Guertin Professor of Natural Product Chemistry

Primary DLC

Department of Chemistry

MIT Room: 18-296

Assistant

Shannon Wagner
wagners@mit.edu

Areas of Interest and Expertise

Polymeric Nanoparticle Structures, with a Particular Interest in Potential Applications in Therapeutics and (Targeted) Drug Delivery

Research Summary

The Johnson laboratory seeks creative, macromolecular solutions to problems at the interface of chemistry, medicine, biology, and materials science. Materials synthesis is approached in an analogous manner to natural-products synthesis; an interesting target structure is chosen and a synthetic scheme is designed to access that structure as efficiently as possible. The targets are designed de novo from careful consideration of the specific needs of a given application and with a particular emphasis on function. The tools of traditional organic and organometallic synthesis, synthetic polymer chemistry, photochemistry, surface science, and biopolymer engineering are combined to realize the designs.

Just as natural-products chemists must often invent new reaction methodologies to access complex structures and their corresponding derivatives, the Johnson lab will seek to develop new methodologies for the construction and modification of complex material libraries. Iterative library synthesis, function-based screening, and design optimization will ultimately yield basic knowledge, such as structure-function relationships for materials in specific applications, and new materials-based technologies that outperform current alternatives. Some examples of target material platforms and their associated applications are: (1) novel, nanoscopic branched-arm star polymer architectures for in vivo drug delivery and supported catalysis, (2) hybrid synthetic-natural hydrogels for correlation of the effects of network microstructure on cell response, and (3) new types of semiconducting organometallic polymers and polymer films for sensing, supported catalysis, and energy conversion.

Recent Work

  • Video

    Antibody–Bottlebrush Pro-drug Conjugates: A Novel Platform for Targeted Theranostics: Prof. Johnson

    November 19, 2025Conference Video Duration: 34:30

    Antibody–drug conjugates (ADCs) are the gold standard for targeted drug delivery systems, but their chemical design imposes constraints that, if addressed, could enable a new generation of cancer therapeutics and imaging modalities. For example, due to bioconjugation limitations, the payload scope of ADCs is restricted to highly potent payloads with inherently unselective mechanisms of action, leading to narrow therapeutic windows and resistance. This seminar will introduce a new platform called Antibody–Bottlebrush prodrug Conjugates (ABCs) that can potentially address these challenges. ABCs feature a modular design that allows drug-to-antibody ratios (DARs) from ~1–135 while maintaining strong target binding, efficient cellular uptake, and favorable pharmacokinetics and biodistribution. Leveraging their capability to access very high DARs, ABCs can carry payloads (e.g., 10-fold less potent than existing ADC payloads) that are insufficiently potent to be used in traditional ADCs, thereby enabling new mechanisms-of-action. Moreover, ABCs are readily amenable to using various payload combinations, release mechanisms, and non-drug (e.g., imaging) agents. ABCs display efficacies on par with or superior to clinical ADCs in preclinical tumor models at clinically relevant payload doses, motivating their further clinical translation.

    1.23.24-Japan-Johnson

    January 23, 2024Conference Video Duration: 34:32
    Designing Large and Small Molecules for Energy, Sustainability, and Healthcare