Formate Economy and AI-Assisted Catalyst Search Ju Li Battelle Energy Alliance Professor, MIT Department of Nuclear Science & Engineering Professor, MIT Department of Materials Science and Engineering
Carbon efficiency is one of the most pressing problems of carbon dioxide electroreduction today. While there have been studies on anion exchange membrane electrolyzers with carbon dioxide (gas) and bipolar membrane electrolyzers with bicarbonate (aqueous) feedstocks, both suffer from low carbon efficiency. In anion exchange membrane electrolyzers, this is due to carbonate anion crossover, whereas in bipolar membrane electrolyzers, the exsolution of carbon dioxide (gas) from the bicarbonate solution is the culprit. Here, we first elucidate the root cause of the low carbon efficiency of liquid bicarbonate electrolyzers with thermodynamic calculations and then achieve carbon-efficient carbon dioxide electro- reduction by adopting a near-neutral-pH cation exchange membrane, a glass fiber intermediate layer, and carbon dioxide (gas) partial pressure management. We convert highly concentrated bicarbonate solution to solid formate fuel with a yield (carbon efficiency) of greater than 96%. A device test is demonstrated at 100 mA cmÀ2 with a full-cell voltage of 3.1 V for over 200 h. ["A carbon-efficient bicarbonate electrolyzer," Cell Reports Physical Science 4 (2023) 101662]
Extracting Value Where Others See Waste Kent S. Sorenson, Jr. Chief Technology Officer, Allonnia
Martin Bazant
Martin Z. Bazant E. G. Roos (1944) Professor, Chemical Engineering and Mathematics