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Decarbonizing Chemical Manufacturing
Yogesh Surendranath
Donner Professor of Science, MIT Department of Chemistry

The chemical industry is the major source of carbon emissions, requiring new technologies for disruptive decarbonization. The direct and selectivity electrochemical synthesis of commodity chemicals from CO2 could play a key role in decarbonizing chemical manufacturing. However, many key chemicals are accessible over a narrow range in electrochemical potential, requiring general design principles for controlling kinetic branching in these reactions. We have uncovered the central role of the reaction environment in facilitating selective CO2 reduction at electrode surfaces and have employed electrolyte design to alter the mechanistic profile of chemical synthesis. Our latest findings in this area will be discussed.